Publications Yvan

Research - Yvan- Members - Publications


« Can the Ti(OiPr)4/nBuLi Combination of Reagents Function as a Catalyst for [2+2+2] Alkyne Cyclotrimerisation Reactions? » G. Siemiaszko, Y. Six*, New J. Chem. 2018, 42, DOI: 10.1039/C8NJ04931A.

« 1,3-Dipolar cycloadditions with azomethine ylide species generated from aminocyclopropanes. » A. Wolan, J. A. Kowalska-Six, H. Rajerison, M. Césario, M. Cordier, Y. Six*, Tetrahedron 2018, 74, doi: 10.1016/j.tet.2018.05.082.


« 2,3-Methanopyrrolidines: Synthesis and Ring-opening Transformations. » Y. Six in Targets in Heterocyclic Systems, O. A. Attanasi, P. Merino, D. Spinelli, Eds.; Società Chimica Italiana: Roma (2017); Vol. 21, Chapter 13, pp. 277−307.

« Synthesis of functionalised azepanes and piperidines from bicyclic halogenated aminocyclopropane derivatives. » C. Chen, P. Kattanguru, O. A. Tomashenko, R. Karpowicz, G. Siemiaszko, A. Bhattacharya, V. Calasans, Y. Six*, Org. Biomol. Chem. 2017, 15, 5364–5372 (open access).


« Ring-opening, cycloaddition and rearrangement reactions of nitrogen-substituted cyclopropane derivatives. » V. A. Rassadin*, Y. Six*, Tetrahedron 2016, 72, 4701–4757.

Graphical abstract2015

« Access to New Endoperoxide Derivatives by Electrochemical Oxidation of Substituted 3-Azabicyclo[4.1.0]hept-4-enes. » F. Nuter, A. K. D. Dimé, C. Chen, L. Bounaadja, E. Mouray, I. Florent, Y. Six*, O. Buriez*, A. Marinetti*, A. Voituriez*, Chem. Eur. J. 2015, 21, 5584–5593.


« Reductive Alkylation of Thioamides with Grignard Reagents in the Presence of Ti(OiPr)4: Insight and Extension. » F. Hermant, E. Urbańska, S. Seizilles de Mazancourt, T. Maubert, E. Nicolas, Y. Six*, Organometallics 2014, 33, 5643–5653.

« Ti(OiPr)4/nBuLi: an attractive reagent system for [2+2+2] cyclotrimerisation reactions. » V. A. Rassadin, E. Nicolas, Y. Six*, Chem. Commun. 2014, 50, 7666–7669.

« Ti-mediated intramolecular cyclopropanation of N-alkenyl thioamides: scope and mechanistic study. » F. Hermant, E. Nicolas, Y. Six*, Tetrahedron 2014, 70, 3924–3930.

« A study of the reaction of nBuLi with Ti(OiPr)4 as a method to generate titanacyclopropane and titanacyclopropene species. » V. A. Rassadin, Y. Six*, Tetrahedron 2014, 70, 787–794.


« Synthesis of polycyclic aminocyclobutane systems by the rearrangement of N-(ortho-vinylphenyl) 2-azabicyclo[3.1.0]hexane derivatives » A. Wasilewska, B. A. Woźniak, G. Doridot, K. Piotrowska, N. Witkowska, P. Retailleau, Y. Six*, Chem. Eur. J. 2013, 19, 11759−11567.


« Kulinkovich-type reactions of thioamides: similar to those of carboxylic amides? » E. Augustowska, A. Boiron, J. Deffit, Y. Six*, Chem. Commun. 2012, 48, 5031–5033.


« Tactics for the asymmetric preparation of 2-azabicyclo[3.1.0]hexane and 2-azabicyclo[4.1.0]heptane scaffolds. » A. Wolan, M. Soueidan, A. Chiaroni, P. Retailleau, S. Py, Y. Six*, Tetrahedron Lett. 2011, 52, 2501–2504.


« Aminocyclopropanes as precursors of endoperoxides with antimalarial activity. » C. Madelaine, O. Buriez*, B. Crousse, I. Florent, P. Grellier, P. Retailleau, Y. Six*, Org. Biomol. Chem. 2010, 8, 5591–5601.

« Synthetic Transformations Mediated by the Combination of Titanium(IV) Alkoxides and Grignard Reagents: Selectivity Issues and Recent Applications. Part 1: Reactions of Carbonyl Derivatives and Nitriles. » A. Wolan*, Y. Six*, Tetrahedron 2010, 66, 15–61.


« Synthetic Transformations Mediated by the Combination of Titanium(IV) Alkoxides and Grignard Reagents: Selectivity Issues and Recent Applications. Part 2: Reactions of Alkenes, Allenes and Alkynes. » A. Wolan*, Y. Six*, Tetrahedron 2010, 66, 3097–3133.

Before 2010

« A convenient titanium-mediated intermolecular alkyne–carbonate coupling reaction. » A. Wolan, F. Cadoret, Y. Six*, Tetrahedron 2009, 65, 7429–7439.

GA Tet 2009

« Diastereoselective Ti-mediated preparation of bicyclic aminocyclopropanes from N‑alkenyl amides. » C. Madelaine, A. K. Buzas, J. A. Kowalska-Six, Y. Six*, B. Crousse, Tetrahedron Lett. 2009, 50, 5367–5371.



« Intramolecular Kulinkovich–de Meijere reactions of various disubstituted alkenes bearing amide groups. » C. Madelaine, N. Ouhamou, A. Chiaroni, E. Vedrenne, L. Grimaud, Y. Six*, Tetrahedron 2008, 64, 8878–8898.


« Electrochemical Aerobic Oxidation of Aminocyclopropanes to Endoperoxides. » C. Madelaine, Y. Six*, O. Buriez*, Angew. Chem. 2007, 119, 8192–8195; Angew. Chem. Int. Ed. 2007, 46, 8046–8049.

« The relative reactivities of various unsaturated compounds towards diisopropyloxy(eta2-cyclopentene)titanium. » F. Cadoret, Y. Six*, Tetrahedron Lett. 2007, 48, 5491–5495.


« Diisopropyloxy(eta2-cyclopentene)titanium for the diastereoselective synthesis of various 1,2-disubstituted cyclopentanes. » F. Cadoret, P. Retailleau, Y. Six*, Tetrahedron Lett. 2006, 47, 7749–7753.


« The intramolecular aromatic electrophilic substitution of aminocyclopropanes prepared by the Kulinkovich-de Meijere reaction. » L. Larquetoux, N. Ouhamou, A. Chiaroni, Y. Six*, Eur. J. Org. Chem. 2005, 4654–4662.

« Product Class 8: Aryl Ketones. » Encyclopedia chapter: J.-M. Campagne*, Y. Six* in Science of Synthesis, J. Cossy Ed.; Thieme: Stuttgart (2005); Vol. 26, pp. 989–1044.


« The formal [3+2+1] cyclisation of cyclopropyl amines with carboxylic anhydrides: a quick access to polysubstituted 2,3,3a,4-tetrahydro-6(5H)-indolone ring systems. » L. Larquetoux, J. A. Kowalska, Y. Six*, Eur. J. Org. Chem. 2004, 3517–3525.

« A study of some molecularly imprinted polymers as protic catalysts for the isomerisation of a-pinene oxide to trans-carveol. » W. B. Motherwell*, M. J. Bingham, J. Pothier, Y. Six, Tetrahedron 2004, 60, 3231–3241.


« On the importance of xanthate substituents in the MADIX process. » M. Destarac*, D. Taton, S. Z. Zard*, T. Saleh, Y. Six, A.C.S. Symposium Series 2003, 854, 536–550.

« Titanium-Mediated Carboxylation of Alkynes With Carbon Dioxide. » Y. Six, Eur. J. Org. Chem. 2003, 1157–1171.

« Studies on the intramolecular Kulinkovich-de Meijere reaction of disubstituted alkenes bearing carboxylic amide groups. » N. Ouhamou, Y. Six*, Org. Biomol. Chem. 2003, 1, 3007–3009.


« A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction. » J.-Y. Lallemand*, Y. Six, L. Ricard, Eur. J. Org. Chem. 2002, 503–513.

« The reaction of dialkoxytitanacyclopropanes and dialkoxytitanacyclopropenes with carbon dioxide. » Y. Six, J. Chem. Soc., Perkin Trans. 1 2002, 1159–1160.


« Recent progress in the design and synthesis of artificial enzymes. » W. B. Motherwell*, M. J. Bingham, Y. Six, Tetrahedron 2001, 57, 4663–4686.


« A new approach to cyclohexenes and related structures. » N. Cholleton, I. Gauthier-Gillaizeau, Y. Six, S. Z. Zard*, Chem. Commun. 2000, 535–536.


« An improvement to the Vaultier tandem sequence: a practical highly stereoselective three-component reaction. » Y. Six, J.-Y. Lallemand*, Tetrahedron Lett. 1999, 40, 1295–1296.


« 1,3-Dienylboronates in Diels-Alder reactions: Part III. » P.-Y. Renard, Y. Six, J.-Y. Lallemand*, Tetrahedron Lett. 1997, 38, 6589–6590.


« What is the reason for the difference in Diels-Alder reactivity of isomeric substituted dienes ? A case involving 1,3-dienylboronates. » G. Ohanessian, Y. Six, J.-Y. Lallemand*, Bull. Soc. Chim. Fr. 1996, 133, 1143–1148.

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